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鑱�(li谩n)绯讳汉锛氬嫉鍏堢敓
闆昏┍锛�021-52655260锛�52655262锛�52655263
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| 鍗＄埦璨讳紤瑭﹀姂鐨勫師鐞嗗強閰嶅埗鏂规硶 |
| 榛炴搳娆℃暩(sh霉)锛�10236 鐧�(f膩)甯冩檪闁擄細2014-07-24 |
鐪炬墍鍛ㄧ煡锛屽崱鐖捐不浼戞硶鏄脯瀹氬悇绋墿璩�(zh矛)涓井閲忔按鍒嗙殑绋柟娉曪紝閫欑ó鏂规硶鑷緸1935骞寸敱鍗＄埦璨讳紤鎻愬嚭鍚�锛岀洿閲囩敤I2銆丼O2銆佸悺鍟躲�佺劇姘碈H3OH(鍚按閲忓湪0.05%浠ヤ笅)閰嶅埗鑰屾垚锛屽苟涓旀婧栧寲绲勭箶鎶婇�欏�嬫柟娉曞畾鐐烘婧栨脯寰噺姘村垎锛屾垜鍊戝湅瀹朵篃鎶婇�欏�嬫柟娉曞畾鐐哄湅瀹舵婧栨脯寰噺姘村垎銆�
銆�銆�1銆佸師鐞嗭細鍦ㄦ按瀛樺湪鏅傦紝鍗虫ǎ鍝佷腑鐨勬按鑸囧崱鐖捐不浼戣│鍔戜腑鐨凷O2鑸嘔2鐢�(ch菐n)鐢熸哀鍖栭倓鍘熷弽鎳�(y墨ng)銆�
銆�銆�(1)I2 SO2 2H2O → 2HI H2SO4; 浣嗛�欏�嬪弽鎳�(y墨ng)鏄�嬪彲閫嗗弽鎳�(y墨ng)锛岀暥纭吀婵冨害閬斿埌0.05%浠ヤ笂鏅�锛屽嵆鑳界櫦(f膩)鐢熼�嗗弽鎳�(y墨ng)銆傚鏋滄垜鍊戣畵鍙嶆噳(y墨ng)鎸夌収鍊嬫鏂瑰悜閫茶锛岄渶瑕佸姞鍏ラ仼鐣�?sh霉)鑶睞鎬х墿璩�(zh矛)浠ヤ腑鍜屽弽鎳�(y墨ng)閬庣▼涓敓鎴愮殑閰�銆傜稉(j墨ng)瀵﹂璀夋槑锛屽湪楂旂郴涓姞鍏ュ悺鍟�锛岄�欐ǎ灏卞彲浣垮弽鎳�(y墨ng)鍚戝彸閫茶銆�
銆�銆�(2)C5H5N H2O I2 SO2 → 2姘閰稿悺鍟�;
銆�銆�纭吀閰愬悺鍟剁敓鎴愮～閰搁厫鍚″暥涓嶇┅(w臎n)瀹�锛岃兘鑸囨按鐧�(f膩)鐢熷弽鎳�(y墨ng)锛屾秷鑰楅儴鍒嗘按鑰屽共鎿炬脯瀹�锛岀偤浜嗕娇瀹冪┅(w臎n)瀹�锛屾垜鍊戝彲鍔犵劇姘寸敳閱囥��
銆�銆�(3)纭吀閰愬悺鍟� CH3OH(鐒℃按)→ 鐢插熀纭吀鍚″暥
銆�銆�鎴戝�戞妸閫欎笂闈笁姝ュ弽鎳�(y墨ng)瀵垚绺藉弽鎳�(y墨ng)寮忕偤锛�
銆�銆�I2锔癝O2锔癈5H5N = 1锔�3锔�10
銆�銆�寰炲弽鎳�(y墨ng)寮忓彲浠ョ湅鍑�1mol姘撮渶瑕�1mol纰�锛�1mol浜屾哀鍖栫～鍜�3mol鍚″暥鍙�1mol鐢查唶鑰岀敘(ch菐n)鐢�2mol姘閰稿悺鍟躲��1mol鐢插熀纭吀鍚″暥銆傞�欐槸鐞嗚珫涓婄殑鏁�(sh霉)鎿�(j霉)锛屼絾瀵﹂殯涓婏紝SO2銆佸悺鍟�銆丆H3OH鐨勭敤閲忛兘鏄亷閲忕殑锛屽弽鎳�(y墨ng)瀹岀暍鍚庡浣欑殑娓搁洟纰樺憟鐝�(xi脿n)绱呮鑹�锛屽嵆鍙⒑瀹氱偤鍒伴仈绲傞粸銆�
銆�銆�2銆佸崱鐖捐不浼戣│鍔戠殑閰嶅埗鑸囨瀹�
銆�銆�鑻ヤ互鐢查唶浣滄憾鍔�锛屽墖瑭﹀姂涓璉2銆丼O2銆丆5H5N(鍚按閲忓湪0.05%浠ヤ笅)涓夎�呯殑鍏嬪垎瀛愭暩(sh霉)姣斾緥鐐�
銆�銆�I2锔癝O2锔癈5H5N = 1锔�3锔�10
銆�銆�閫欑ó瑭﹀姂鏈夋晥婵冨害鍙栨焙浜庣鐨勬績搴︺�傛柊閰嶅埗鐨勮│鍔戝叾鏈夋晥婵冨害涓嶆柗闄嶄綆锛屽叾鍘熷洜鏄敱浜庤│鍔戜腑鍚勭祫鍒嗘湰韬篃鍚湁浜涙按鍒�锛屼絾瑭﹀姂婵冨害闄嶄綆鐨勪富瑕佸師鍥犳槸鐢变簺鍓弽鎳�(y墨ng)寮曡捣鐨勶紝杓冮珮娑堣�椾簡閮ㄥ垎纰�銆傞�欎篃瑾槑浜嗛厤鍒堕�欑ó瑭﹀姂瑕佸柈閰�锛屽垎鐢蹭箼鍏╃ó瑭﹀姂骞朵笖鍒嗗垾璨瓨锛岃嚚鐢ㄦ檪鍐嶆贩鍚�锛岃�屼笖瑕佹瀹氥�� |
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